Product ID:1554; 421-77A; PHOTO PRINT FIXER & REPLENIS
MSDS Date:07/27/1992
FSC:6750
NIIN:01-354-2816
MSDS Number: BPXBW

CLAYTON CHEMICAL COMPANY

13310 S. FIGUEROA ST.
LOS ANGELES, CA 90061
US

Emergency Phone: 213-538-9530

Info Phone: 213-538-9530

Cage: 61803

CLAYTON CHEMICAL CO., A DIV OF VARICHEM CORP

276-Z HEATHSVILLE, VA 22473 US

Telephone: 703-759-9399

Cage: 6W820

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

Fraction By Weight: 55-75%

SODIUM BISULFITE (SASA III)

CAS: 7631-90-5

RTECS: VZ2000000

Fraction By Weight: 1-4%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID (SARA III)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 1-3%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRODUCT MAY CAUSE SEVERE IRRITATION
AND BURNS TO BODY TISSUES WHICH IT CONTACTS. INHALATION OF MISTS
OR VAPORS IS HIGHLY UNLIKELY DURING ANY NORMAL USEAGE.
Explanation of Carcinogenicity:THIS CHEMICAL IS NOT LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES:SEVERE IRRITATION OR BURNS. SKIN:POSSIBLE
IRRITATION, BURNS. INHALED:UNLIKELY EXPOSURE BUT MAY CAUSE
RESPIRATORY IRRITATION IF MISTS ARE INHALED. INGESTED:SEVERE
IRRITATION OF THE DIGESTIVE TRAC T.
Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN ON MSDS BY
MFR.

First Aid:INHALATION:REMOVE TO FRESH AIR. EYES:IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR 15 MINUTES. GET PROMPT MEDICAL ATTENTION.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF WATER FOR 15
MINUTES. I NHALED:FOR OVEREXPOSURE, REMOVE TO FRESH AIR.
INGESTION:DRINK MILK OR WATER. INDUCE VOMITING. GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point:NON-FLAMMABLE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:ANY EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:WHEN HEATED TO CECOMPOSITION EMISSION OF
TOXIC FUMES OF SO2 IS POSSIBLE.

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMEMT.
DIKE SPLL. PREVENT FROM ENTERING SEWERS, WATERWAYS OR LOW AREAS.
SOAK UP WITH SAND, OIL DRY OR OTHER ABSORBENT MATERIAL.
Neutralizing Agent:POWDERED SODIUM BICARBONATE

Handling and Storage Precautions:STORE IN WELL VENTILATED AREA. KEEP
CONTAINERS TIGHTLY CLOSED. DO NOT STORE WITH INCOMPATABLE
MATERIALS.
Other Precautions:DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN
AREA WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL.

Respiratory Protection:NO INFORMATION GIVEN ON MSDS BY MFR. SUFFICIENT
ROOM VENTILATION
Ventilation:SUFFICIENT ROOM VENTILATION
Protective Gloves:RECOMMENDED
Eye Protection:EYEGLASSES W/ SIDE SHIELDS
Other Protective Equipment:APRON. (SPLASH PROTECTION IS ALL THAT IS
RECOMMENDED BY MANUFACTURER.)
Work Hygienic Practices:MFR: ? HMIS:USE GOOD CHEMICAL HYGIENE
PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
NONE

HCC:C3
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:AS WATER
Vapor Density:AS WATER
Spec Gravity:1.34
pH:5.7
Evaporation Rate & Reference:SAME AS WATER
Solubility in Water:100%
Appearance and Odor:CLEAR AND COLORLESS, ODOR OF MILD VINEGAR

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, OXIDIZERS
Stability Condition to Avoid:NO INFORMATION GIVEN ON MSDS BY MFR.
Hazardous Decomposition Products:OXIDES OF SULFUR, CO2, CARBON
MONOXIDE, AMMONIA
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:RECOVER NON-USEABLE FREE LIQUID AND/OR
CONTAMINATED WATER AND DISPOSE OF IN AN APPROVED/PERMITTED
TREATMENT SYSTEM AND SOLIDS TO AN APPROVED/PERMITTED LANDFILL.
DISCHARGE TO SEWER REQUIRES APPROVAL OF PERMITTING AUTHORITY AND
MAY REQUIRE PRETREATMENT

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.